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Iron(II) fluoride
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・ Iron(II) gluconate
・ Iron(II) hydride
・ Iron(II) hydroxide
・ Iron(II) iodide
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・ Iron(II) molybdate
・ Iron(II) oxalate
・ Iron(II) oxide
・ Iron(II) phosphate
・ Iron(II) selenide
・ Iron(II) sulfate
・ Iron(II) sulfide
・ Iron(II,III) oxide


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Iron(II) fluoride : ウィキペディア英語版
Iron(II) fluoride

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Iron(II) fluoride (also ferrous fluoride) is the inorganic compound with formula FeF2. It is a green high-melting solid. The name iron(II) fluoride also applies to hydrates FeF2·4H2O.
==Structure and physical properties==
Like many difluorides, FeF2 adopts the TiO2 rutile structure wherein the iron centers are octahedrally and the fluoride ions three coordinate.〔 The Fe-F bond lengths are 2.03 and 2.10 Å.
Low temperature neutron diffraction studies show that the material is antiferromagnetic. Heat capacity measurements reveal an event at 78.3 K corresponding to ordering of antiferromagnetic state.
The vapor species were identified between 965 and 1149 K. Using mass spectrometry the heat of sublimation was experimentally determined and averaged to be 75.56 ± 0.23 kcal. mole−1.
The following reaction was proposed in order to calculate the atomization energy for Fe+:〔
:FeF2 + e → Fe+ + F2 (or 2F) + 2e

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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